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I suggest if you do want to try it, read up on taking niacin. It can cause a flush which is very uncomfortable and if you don't know it is coming, it is scary.
It's possible to completely go off diet soda. I haven't had one in almost two years. It was hard - I went cold turkey for two weeks as a test of willpower - and when I tried to have one later it tasted like chemical soup! I do drink some caffeine now, just not with artificial sweeteners.